RTFM
Requirements
In order to use PHP's CURL functions you need to install the libcurl package. PHP requires that you use libcurl 7.0.2-beta or higher. In PHP 4.2.3, you will need libcurl version 7.9.0 or higher. From PHP 4.3.0, you will need a libcurl version that's 7.9.8 or higher. PHP 5.0.0 requires a libcurl version 7.10.5 or greater.
Installation
To use PHP's CURL support you must also compile PHP --with-curl[=DIR] where DIR is the location of the directory containing the lib and include directories. In the "include" directory there should be a folder named "curl" which should contain the easy.h and curl.h files. There should be a file named libcurl.a located in the "lib" directory. Beginning with PHP 4.3.0 you can configure PHP to use CURL for URL streams --with-curlwrappers.
Note to Win32 Users: In order to enable this module on a Windows environment, libeay32.dll and ssleay32.dll must be present in your PATH.
You don't need libcurl.dll from the CURL site.